48487
Accession Number
28451
Author
Nissan, Alfred H.
Title Of Article Chaper
Density of Hydrogen Bonds in H-Bond Dominated Solids
Title Of Journal Book
Macromolecules
Volume
10
Pages
660-662
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Hydrogen-bond dominated solids belong to the class of solids the elastic properties of which, either in theoretical analysis or experimental studies, are found to be related in the first approximation to the density and characteristics of the hydrogen bond with only minor or negligible contributions from covalent, ionic, or van der Waals' bonds or from entropic changes. For such solids, previous work determined the E=kN<sup>1</sup>/3</sup> where E is Young's modulus in dyn/cm<sup>2</sup>, N is the number of H bonds per cm<sup>3</sup> effectively carrying the load and k id a constant equal to 7. 8x10<sup>3</sup> for OH --- O bonds occurring in cellulosics based on H-bond dissociation energy of 4.5 kcal/mol, internuclear distance of 2.7A, and a Morse function for the bond potential. In this paper, the value of k is determined from an independent source. By using calculations carried out by Dr. Richard E. Mark and his colleagues at Syracuse University for the three moduli of elasticity for cellulose crystallites, k was calculated for a sheet of randomly oriented crystallites and was found to be (9.7±1.6)x10<sup>3</sup> dyn/cm. It is concluded that k probably equals 8.7x10<sup>3</sup> dyn/cm, with an uncertainty of approximately 20per thousand.
Keywords
hydrogen;bond;solid
pub_id
48487