48233
Accession Number
5202
Author
Yamasaki, Kazuo; Murozumi, Masayo; Nakamura, Seiji; Hinata, Makoto; Yuasa, Mitsuaki
Title Of Article Chaper
Lead isotope ratios in Japanese galena ores and archaeological objects
Title Of Journal Book
Nippon Kagaku Kaishi
Issue
8
Pages
1112-1117
Language Of Text
Japanese
Literature Type
Serial
Literature Level
Analytic
Abstract
Pb isotope ratios <sub>206</sub>Pb:<sub>204</sub>PB, <sub>207</sub>Pb:<sub>204</sub>Pb, <sub>208</sub>Pb: <sub>204</sub>Pb, <sub>207</sub>Pb:<sub>206</sub>Pb, and <s208 >sPb:<sub>206</sub>Pb in Japanese galena ores and archaeological bronze objects were determined by mass spectrometry using a Re single filament as a surface ionization device. Basic experimental conditions including detection limits, fractionation effects, memory effects, etc., were examined, and the accuracy of the determination was checked using a shelf standard. Archaeological bronze objects were dissolved in HNO<sub>3</sub> and Pb was extracted by the dithizone method. When 0.5 mug Pb was loaded on the Re filament with H<sub>3</sub>PO<sub>4</sub> and silica gel as stabilizers, an ion current of 10<sub>-13</sub>-10<s-15> s A due to Pb+ was obtained and maintained stable for several h. Relative standard deviations for the isotope ratios <sub>207</sub>Pb: <sub>206</sub>Pb and <sub>208</sub>Pb: <sub>206</sub>Pb were 0.1-0.5%. Pb isotope ratios were given for 17 Japanese galena ores and for archaeological bronze objects such as bronze bells, halberds (Yayoi period), Horyuji pagoda spire (7th century), and Northern Sung coins (11th century). A close resemblance of the isotope ratios was found between Japanese galena ores andsome Japanese bronze objects of the 7th century, suggesting the use of the former as raw materiais for the latter. See aiso 14-1279. -- AATA
pub_id
48233