47818
Accession Number
32247
Title Of Article Chaper
Newsprint deterioration: The influence of temperature on the relative contribution of oxygen-independent and oxygen-dependent processes in the total rate
Title Of Journal Book
Tappi: The Journal of the Technical Association of the Pulp and Paper Industry
Volume
63
Issue
1
Pages
75-77
Collation
3 p. : ills.
Reference Bibliography
Includes bibliographic references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Both atmospheric oxidation and a process that proceeds independently of oxygen were found to contribute significantly to the deterioration of newsprint at several temperatures between 120[degree]C and 60[degree]C in sealed tubes maintained at 100% RH. The ratio, i, of the oxygen-independent process to the total rate of deterioration was determined at each temperature, and Arrhenius activation energies were determined for both the atmospheric oxidation and the oxygen-independent process as well as for the total rate of deterioration. A relationship between i and the absolute temperature was derived and was used to extrapolate the data to 20[degree]C. The results indicate that i is significantly dependent on temperature and that the relative importance of atmospheric oxidation to the overall rate of deterioration decreases as the testing temperature is lowered. Therefore, accelerated aging tests performed near 100[degree]C may lead to misleading conclusions regarding the chemical process responsible for the degradation of paper at room temperature.
Keywords
newsprint;paper;aging;oxidation;kinetics;yellowing;tensile;strength;degradation;temperature
pub_id
47818