In a set of composite samples of oil or alkyd paints, over acrylic grounds, naturally aged for eight years, some of the samples delaminated. Samples were analyzed with X-ray fluorescence (XRF), inductively coupled plasma (ICP), Fourier transform infrared – attenuated total reflectance (FTIR-ATR) and atomic force microscopy (ATM), as well as other techniques not detailed in this paper. Results indicate the main cause of delamination is metal soaps in the oil paint and particularly zinc soaps. The ground is a minor consideration as well, rougher grounds providing better adhesion than smooth ones.