48490
Accession Number
28455
Title Of Article Chaper
The Penetration of Solutes into Swollen Gel Layers
Title Of Journal Book
The Journal of Photographic Science
Volume
24
Issue
44322
Pages
193-196
Collation
4 p. : ill.
Reference Bibliography
Includes bibliographical references
Publisher City
London
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
The times of penetration of 1M sodium thiosulphate and D163 developer at full strength and diluted were measured through gelatin coatings of 4.6, 10.5 and 20 mu, dry thickness, with a thin underlayer of silver chloride emulsion as an indicator. The results show that the time of penetration is proportional to the product of the thickness of the swollen layer and the cube of the reciprocal of the proportion of water in the gel. For layers of gelatin of up to 20 mum, swollen to any extent of practical importance, the penetration is non-Fickian; the solute moves with constant velocity through the depth of the layer, presumably as a front of constant concentration gradient.
Keywords
penetration; solute; gel; layer
pub_id
48490