48095
Accession Number
26017
Author
Burgess, Helen D.
Editor
Grimstad, Kirsten
Author Affiliation
Canadian Conservation Institute
Title Of Article Chaper
The stabilization of cellulosic fibres by borohydride derivatives
Title Of Journal Book
ICOM Committee for Conservation, 9th triennial meeting, Dresden, German Democratic Republic, 26-31 August 1990: preprints
Pages
447-452
Collation
2 figs., 2 tables
Reference Bibliography
17 refs.
Publisher
ICOM Committee for Conservation
Publisher City
Paris
ISBN
0-89236-185-9
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph : Proceedings
Literature Level
Analytic
Meeting
ICOM Committee for Conservation. Meeting
Meeting City
Dresden
Meeting Country
German Democratic Republic
Abstract
This article summarizes research into the stabilization of rag paper (ca. 1899) through immersion treatment with 100 mM sodium and tetraethylammonium borohydride. The effect of prior aqueous deacidification with magnesium bicarbonate upon the permanence of cellulose was also explored. Data were obtained through analysis (viscometric average degree of polymerization using the solvent cadoxen) of treated samples before and after humid accelerated thermal aging (70°C, 50% relative humidity for 84 days). Results demonstrated that borohydride treatments can significantly improve the long-term stability of cellulose. Data analysis revealed the importance of removing ketone and aldehyde carbonyls from oxidized cellulose prior to viscometric analysis with alkaline cellulose solvents.
Keywords
paper; rag paper; deacidification; magnesium bicarbonate; permanence; cellulose; stabilizing; borohydride
pub_id
48095
Meeting Date
19900826-19900831