46574
Editor
Vandiver, Pamela B.; Goodway, Martha; Mass, Jennifer L.
Title Of Article Chaper
Reproduction of Japanese Traditional Pigment Based on Iron Oxide Powders with Yellowish Red Color
Title Of Journal Book
Materials Issues in Art and Archaeology VI: Symposium held November 26-30, 2001, Boston, Massachusetts, USA
Volume
712
Pages
435-440
Collation
6 p. : ills.
Reference Bibliography
Includes bibliographic references
Publisher
Materials Research Society
Publisher City
Warrendale
ISBN
1-55899-648-6
Language Of Text
English
Literature Type
Monograph
Literature Level
Analytic
Abstract
Since the beginning of the 18th century A.D., an artificial iron oxide pigment (hematite, called bengara in Japanese) and having a beautiful yellowish red color, has been produced in Japan and applied to pottery, textiles and paintings. However, in 1965 the traditional bengara could not be produced anymore, mainly because of environmental pollution. The purpose of this study is to make clear the features of traditional bengara and to reproduce high quality bengara using modern high-purity reagents. Traditional bengara has been characterized as hematite containing a small amount of Al. The average size of the bengara particles is approximately 100 nm. The color becomes more yellowish-red with increasing Al content. A monophase of hematite prepared by heating a mixture of FeSO4-7H2O and ?-Al2O3 to about 680°C included a small amount of Al substituted in a solid solution. The particle size greatly decreased as the heat treatment temperature was decreased: 100nm at 770°C but 50 nm at 650°C. The color of the particles becomes more vivid as the temperature is decreased, but within bounds this color is independent of the amount of Al in solid solution.
Keywords
Japanese; traditional; pigment; iron; oxide; powder; color
pub_id
46574