43972
Accession Number
16966
Title Of Article Chaper
Fundamental algorithm between concentration and intensity in XRF analysis. 1 - Theory
Title Of Journal Book
X-Ray SPECTROMETRY
Volume
13
Issue
3
Pages
115-120
Collation
2 tables
Reference Bibliography
Bibliography: p. 120
Literature Type
Serial
Literature Level
Analytic
Abstract
An algorithm is proposed to correct matrix effects in x-ray fluorescence analysis. Deduced from Sherman's equations, it includes a new algorithm between concentration and intensity, and explicit expressions permitting the calculation of Ü8<sub>ij</sub> and rho<sub>ij</sub> coefficients that correct for absorption and enhancement effects, respectively. In part 2, the algorithm is adapted to practical situations. From an estimate of composition calculated by the Claisse-Quinin algorithm and an appropriate calibration, the algorithm is used to refine the estimated composition for greater accuracy. This approach is equivalent to the fundamental parameters method but is presented in a simpler version adaptable to any mini-computer.
Keywords
xray fluorescence;analysis
pub_id
43972