43740
Accession Number
28007
Author
Heinrich, Kurt F.J.;Yakowitz, Harvey
Author Affiliation
National Bureau of Standards. Institute for Materials Research
Title Of Article Chaper
Absorption of Primary X Rays in Electron Probe Microanalysis
Title Of Journal Book
Analytical Chemistry
Volume
47
Issue
14
Pages
2408-2411
Collation
4 p. : ill.
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Available experimental evidence concerning absorption in x-ray targets, corrected for fluorescence due to the continuum, is generalized to give the formula, f<sub>p</sub>=(1+agammachi)<sup>-2</sup>, in which f<sub>p</sub> is the primary x-ray absorption factor, gamma=(E<sub>o</sub><sup>1.65</sup>- E<sub>q</sub><sup>1.65</sup>), E<sub>o</sub>(kV) is the operating voltage, E<sub>q</sub>(kV) the critical excitation voltage, chi=mu cosec psi, mu is the mass absorption coefficient for the respective target and line, psi is the x-ray emergence angle, and a=1.2x10<sup>-6</sup> g/cm<sup>2</sup>. The presumed effect of the atomic number of the target on f<sub>p</sub> is overestimated by Philibert's formula. It is smaller than the statistical spread of experimental data, and can therefore be neglected.
Keywords
absorption;x-ray;electron;probe;microanalysis
pub_id
43740