43537
Title Of Article Chaper
Detection of an epoxy-resin coating on a seventeenth-century painting
Title Of Journal Book
Studies in conservation
Volume
9
Issue
1
Pages
44204
Language Of Text
English
Language Of Summary
French
Literature Type
Serial
Literature Level
Analytic
Abstract
A detailed examination was made of a painting from which small portions of the varnish had been accidently pulled away from the surface. Beneath a thin coating of readily-soluble varnish, there was found a second coating, insoluble in all of the common solvents, which had separated from the paint in a few places. Xylene was able to penetrate beneath to this insoluble coating and to soften and swell the paint, permitting sheets of the coating to be pulled away with tweezers. Examination of these samples by infrared spectroscopy revealed that it was an epoxy resin. The evidence of this examination suggests that a genuine, but somewhat abraided, 17th century painting had been overpainted in a fuller range of color and chiaroscuro to improve its appearance and that new cracks had been cleverly incised over the original cracks. Finally, the work had been covered with a tough, insoluble epoxy resin, apparently to prevent detection of the readily soluble fresh paint. As a consequence, preliminary tests with solvents and examination by ultraviolet and infrared photography and by x-ray did not immediately arouse suspicion of extensive overpainting. This use of an insoluble epoxy resin and the precision of its identification by infrared spectroscopy is called to the attention of colleagues.
Keywords
Painting, examination; synthetic-resin, epoxy; painting, authenticity forgery; spectroscopy, infrared absorption; painting, microscopy; ICCROM
pub_id
43537