40342
Accession Number
6033
Title Of Article Chaper
Corrosion problems in Greece and the contributions to their solution by the Laboratory of Physical Chemistry and Applied Electrochemistry of the National Technical University of Athens
Title Of Journal Book
British corrosion journal
Volume
14
Issue
2
Pages
61-68
Collation
12 photos
Literature Type
Serial
Literature Level
Analytic
Abstract
The highly polluted and salt-laden atmosphere of Greece is discussed, in relation to damaging effects on metals, ancient monuments and statues. The marble statues are crusted with gypsum (CaSO<sub>4</sub> . 2H<sub>2</sub>O) if sheltered, or pitted and cracked if exposed to rain. Bacteria and deposits of colloidal particles further destroy the marble and gypsum. Steel reinforcements, now corroded, are causing cracks in stonework, and titanium replacements are recommended. Chemical methods of Converting gypsum to CaCO<sub>3</sub> are being developed; one employing CO<sub>2</sub> at eight atmospheres and 70°C is successful, provided the statues may be transported. Thirty types of protective coating were tried, and rejected. Acetone-soluble biocides can be used but the particulate deposits cannot yet be removed. An appendix lists proposed conservation measures: removal of many statues to climatized museums is recommended. -- AATA
pub_id
40342