39676
Accession Number
18866
Author
Freiman, S.W.
Title Of Article Chaper
Effects of Chemical Environments on Slow Crack Growth in Glasses and Ceramics
Title Of Journal Book
Journal of Geophysical Research
Volume
89
Issue
6B
Pages
4072-4076
Collation
6 figures
Reference Bibliography
Bibliog.: p.4076
Publisher
American Geophysical Union
Publisher City
Washington
Language Of Text
English
Language Of Summary
English
Literature Type
Serial
Literature Level
Analytic
Abstract
This paper presents a review of our current understanding of environmentally induced slow crack growth in glasses, single crystals, and polycrystalline ceramics. It is shown that the rate of crack growth is controlled by the chemical activity of the active species in the environment as sell as by the stress intensity at the crack tip. A recently developed molecular model of stress-induced chemical reaction between vitreous silica and water is described. The implicaions of this model for the effects of other chemical species on crack growth are discussed. Finally, the complications introduced by the presence of grain boundaries in polycrystalline ceramics are pointed out. Analysis of glass decay can aid in its conservation.
Keywords
glass;polycrystalline ceramics;crack growth;reaction rate theory
pub_id
39676