39514
Accession Number
8882
Title Of Article Chaper
Degradation of chain molecules. 1. Exact solution of the kinetics equations
Title Of Journal Book
Macromolecules
Volume
14
Issue
3
Pages
654-658
Literature Type
Serial
Literature Level
Analytic
Abstract
A general solution of the rate equations representing the degradation of chain molecules is given. The treatment may be applied to any set of equations and to any initial distribution. Model calculations are performed for random scission, Gaussian probability of scission, and scission exclusively at the mid point of the chain. The starting MWD is of the Schulz type, differing in non-uniformity. Results demonstrate that, by fitting the model parameters to experimental distributions, full kinetic infonnation on the degradation process may be obtained. -- AATA
pub_id
39514