38965
Accession Number
36032
Title Of Article Chaper
The Formation of Copper Fibers During the Lime-Enhanced Hydrogen Reduction of Cuprous Sulfide
Title Of Journal Book
Metallography
Volume
14
Issue
4
Pages
335-345
Collation
11 p. : ills.
Reference Bibliography
Includes bibliographic references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Morphological features of the lime-enhanced hydrogen reduction of cuprous sulfide pellets were investigated as a function of temperature and time by scanning electron microscopy. Moderate temperatures of reduction (600-750[degrees]C) were found ti result in the formation of fibers and loops of copper, whereas at high temperatures of reduction (900-1000[degrees]C) only sintered crusts of spongy copper were obtained. The sequence of nucleation and growth of copper fibers was found to be the formation of pits and pores on the sulfide particles, followed by the nucleation of copper preferentially in these pores, the emergence of copper hairs from the sulfide base, and the formation and thickening of loopy fibers. These events are explained on the basis of the reduction characteristics and nonstoichiometry of cuprous sulfide and its mismatch with the product metal. While lime enhances the bulk reduction rate of cuprous sulfide, it does not seem to affect the mechanism of copper fiber formation.
Keywords
copper;fiber;formation;hydrogen;suprous;sulfide
pub_id
38965