38454
Author
Narain Singh, Devandra Deo;Yadav, Shyam Jit;Pandya, Achal;Singh Panwar, Kirtipal
Editor
Bridgland, Janet
Author Affiliation
National Metallurgical Laboratory;National Metallurgical Laboratory;National Museum Institute;City Palace Museum
Title Of Article Chaper
Unfolding the mystery of the non-rusting behaviour of Damascus steel
Title Of Journal Book
ICOM Committee for Conservation, ICOM-CC, 15th Triennial Conference New Delhi, 22-26 September 2008: preprints
Volume
1
Pages
447-456
Collation
10 p. : ills.
Reference Bibliography
Includes bibliographic references
Publisher
Allied Publishers Pvt.
Publisher City
New Delhi
ISBN
9.79E+12
Language Of Text
English
Literature Type
Monograph
Literature Level
Analytic
Abstract
The mystery of the non-rusting behaviour of weapons made from Damascus steel is discussed. Raman spectroscopy, electrochemical impedance spectroscopy, polarisation studies, image analysis and hardness tests were performed to understand the causes of this behaviour. Ferro-ferricyanide tests were conducted to demonstrate resistance to the onset of corrosion by Damascus and other steels. The studies show that the resistance to rusting by weapons made from Damascus steel is due to the presence of a rich cementite phase formed on their surface by special heating, cooling and etching treatments of the surface. Polarisation and electrochemical impedance studies indicate that the oxygen reduction reaction is slower on a cementitecovered surface. This causes the weapons to corrode at a slower rate.
Keywords
Damascus;steel;Raman;spectroscopy;cementite;non-rusting;ferro-ferricyanide;test;impedance
pub_id
38454