37165
Accession Number
30376
Author
Chen, Wencan; Wee, Pamela; Brindle, Ian D.
Title Of Article Chaper
Elimination of the memory effects of gold, mercury and silver in inductively coupled plasma atomic emission spectroscopy
Title Of Journal Book
J. Anal. At. Spectrom.
Volume
15
Pages
409-413
Collation
5 p. : ills.
Reference Bibliography
Includes bibliographic references
Literature Type
Serial
Literature Level
Analytic
Abstract
The memory effects of mercury, gold and silver are eliminated by the use of sulfur containing complexing agents. In low concentrations (1 ?g ml-1) of mercury and gold, the addition of 2% L-cysteine gives wash-out times of less than 1 min for both elements. At higher concentrations of gold and mercury, and at low concentrations of silver, the reagent is less effective. Thiourea, at a concentration of 1%, eliminates the memory of silver, also giving wash-out times of approximately 1.5 min. The use of thiourea with higher concentrations (100 ?g ml-1) of mercury and gold delivers wash-out times of 1 min and 2 min respectively. In a matrix similar to that found in many samples, the wash-out time for gold is less that 3.5 min and less than 2 min for mercury.
Keywords
gold; mercury; silver; inductively; coupled; plasma; atomic; emission; spectroscopy; icp
pub_id
37165