37140
Accession Number
33048
Title Of Article Chaper
Hydrogen plasma reactions in a D.C. mode for the conservation of iron meteorites and antiquities
Title Of Journal Book
Studies in conservation
Volume
36
Issue
3
Pages
161-171
Collation
6 figs., 5 tables
Reference Bibliography
24 refs.
ISSN
0039-3630
Language Of Text
English
Language Of Summary
English;French;German
Literature Type
Serial
Literature Level
Analytic
Abstract
Reports that four iron meteorite fragments and 13 archaeological iron objects were exposed to a low pressure hydrogen plasma for up to two weeks in a pilot apparatus. In the experiment the objects acted as cathodes in a 600-1600V dc electrical field. While the chlorine-containing beta-FeOOH, akaganeite, was present in all objects before the test, no akaganeite and no chlorides were present afterwards. The objects, including one meteorite which had been exposed for more than 5000 years to seawater, were found to be stable after the glow discharge treatment. The major mineral after treatment was identified as magnetite, and the objects generally assumed an iron gray surface color. No sputtering and no reduction to free iron took place under the test conditions, operating at or below 120°C and at pressures of 0.4-1 mb hydrogen.
Keywords
Conservation Information Network;iron;metal;magnetite
pub_id
37140