34608
Accession Number
18287
Author
Grignon, J.; Scallan, A.M.
Author Affiliation
Pulp and Paper Research Institute of Canada
Title Of Article Chaper
Effect of pH and neutral salts upon the swelling of cellulose gels
Title Of Journal Book
Journal of applied polymer science
Volume
25
Issue
2
Pages
2829-2843
Reference Bibliography
Bibliog.: p. 2843
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
The swelling of cellulose gel is considered to be caused by an osmotic pressure differential resulting from a difference in concentration of mobile ions between the interior of the gel and the exterior solution. The fundamental feature within the gel, bringing about the unequal distribution, is the presence of ionizing acidic groups attached to the macromolecular network. Using the Donnan theory to describe the distribution of ions, it is shown that the experimentally observed decreases in swelling brought about by extremes of pH and by salt addition may be explained in a semiquantitative way. The swelling behavior of superabsorbent gels appears to be almost completely governed by the proposed mechanism. For conventional wood pulps, the mechanism describes the smaller variations in swelling caused by pH and salt addition. For these gels, electrolytic effects are only responsible for a fraction of the total swelling - the remainder being associated with the macromolecular network itself. The unequal distribution of hydrogen ions between a gel and an exterior solution is described briefly, along with the effect that this has on the potentiometric titration of the gel. -- AATA
Keywords
washing study;swelling CAL
pub_id
34608