34251
Accession Number
29400
Editor
Vandiver, Pamela B.; Druzik, James R.; Galván Madrid, José Luis; Freestone, Ian C.; Wheeler, George Segan
Title Of Article Chaper
Accelerated vs. natural aging: effect of aging conditions on the aging process of cellulose
Title Of Journal Book
Materials issues in art and archaeology IV: symposium held May 16-21, 1994, Cancun, Mexico
Pages
247-270
Collation
11 figs., 3 tables, 13 refs.
Publisher
Materials Research Society
ISBN
1-55899-252-9
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph
Literature Level
Analytic
Abstract
Discusses the kinetics of aging and its implications for the evaluation of changes in the aging process, especially as applied to accelerated aging. The problem of comparing accelerated aging conditions is shown to be separate from that of evaluating changes occurring under one specific set of conditions. Thus tests and measurements that can be used to evaluate the results of a specific accelerated aging experiment are not necessarily valid for use in determining whether two sets of aging conditions is comparable to, or accurately simulates, natural aging. The criteria for comparing two sets of aging conditions are defined and applied to the problem of evaluating accelerated aging conditions. Data from the analysis of individual reaction products of artificially aged paper samples are used to determine the effects of temperature and relative humidity (RH) on the rates of individual reactions. Changes in the distribution of reaction products are used as indicators of changes in the aging process. The aging process of cellulose under the conditions studied (60-90°C, 30-80% RH) is shown to be RH dependent, but relatively temperature independent. Thus raising the temperature at constant RH speeds up the aging process without significantly altering it. If the RH is changed, then the aging process is altered and equivalent states of aging cannot be reached. Accelerated aging should be conducted at the same relative humidity as the conditions to which the results are to be applied. The data also indicate that lowering the relative humidity from 50% to 30% slows the rate of hydrolysis by a factor of three to five. -- AATA
Keywords
accelerated aging;cellulose;relative humidity;temperature -- AATA
pub_id
34251