31850
Author
Geyh, Mebus A.
Title Of Article Chaper
Radiocarbon dating problems using acetylene as counting gas
Title Of Journal Book
Radiocarbon
Volume
32
Issue
3
Pages
321-324
Collation
2 figs., 1 table
Reference Bibliography
refs.
ISSN
0033-8222
Language Of Text
English
Language Of Summary
English
Literature Type
Serial
Literature Level
Analytic
Abstract
An investigation of inconsistent Hannover results in the International Collaborative Study (ICS) led to the conclusion that the main reason was contamination of the acetylene used as counting gas with recent and/or fossil carbon by the lithium used for its preparation. Despite the high level of purity of the lithium guaranteed by the producer and storage under argon in cans, different charges were partly covered with contemporary lithium carbonate and fossil oil sometimes was used to preserve the metal. Thorough cleaning of the surface of the lithium rods decreased the contamination but did not remove it entirely, which is evidenced in the wider scatter of the counting rates of various background gases than that of radiocarbon-free tank acetylene. As a result of the high risk of contamination with fossil and/or recent carbon from the acetylene counting gas, the high price of lithium, and the time-consuming preparation, the Hannover Carbon-14 Laboratory will use carbon dioxide instead of acetylene as counting gas in the future.
Keywords
radiocarbon dating;counting gas;contamination;fossils;carbon; sample preparation;acetylene;International Collaborative Study;lithium; carbon dioxide
pub_id
31850