30394
Accession Number
25802
Author
Michalski, Stefan
Editor
Mills, John S.; Smith, Perry
Author Affiliation
Canadian Conservation Institute
Title Of Article Chaper
A physical model of the cleaning of oil paint
Title Of Journal Book
Cleaning, retouching and coatings: technology and practice for easel paintings and polychrome sculpture: preprints of the contributions to the Brussels Congress, 3-7 September 1990
Pages
85-92
Collation
7 figs., 3 tables
Reference Bibliography
Includes 72 bibliog. refs.
Publisher
International Institute for Conservation of Historic and Artistic Works
Publisher City
London
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph : Proceedings
Literature Level
Analytic
Meeting
The International Institute for Conservation of Historic and Artistic Works Brussels Congress
Meeting City
Brussels
Meeting Country
Belgium
Abstract
Cleaning science barely exists. This article reviews the scattered data, and assembles a partial model of the physical aspects of varnish removal from oil paint. Organic solvents diffuse into varnish or paint as a swelling front penetration time varies as the square of thickness. Capillary penetration is a separate issue. A chart of solvent penetration vs. time is given, based on the data of Graham and Stolow. During swabbing, slow penetrating solvents can swell more paint than fast ones if the dissolution rate for the varnish is too slow. Data from five authors on swelling of linseed oil are compared. The data will not fit the Teas chart, but they do fit a three-dimensional solubility parameter space. Swelling and leaching of moderately aged paints are substantial; however, this may not be so for very old paint and this requires study. Water takes days to diffuse through pure oil medium but it can channel along flocculated pigment surfaces in minutes. Adsorption of solvents by pigments can cause debonding of the medium, which may explain some blanching or color lifting. Alcohols and water prefer inorganic pigments, while ketones and less polar solvents prefer organic pigments.
Keywords
clean;oil;painting;pigment;varnish;solvent;organic;inorganic -- CAL
pub_id
30394
Meeting Date
19900903-19900907