26872
Accession Number
20118
Author
Drazic, Dragutin M.; Hao, Chen Shen
Title Of Article Chaper
Inhibition of the anodic dissolution of fron in alkaline solution by metal complex irons
Title Of Journal Book
Corrosion science
Volume
23
Issue
7
Pages
683-686
Literature Type
Serial
Literature Level
Analytic
Abstract
The possible inhibiting effects of GaO<sup<sup>b>3<s3-</sup>, GeO<sup>2-</sup>, CrO<sup<sup>b>2<s2-</sup>, and MoO<sup<sup>b>4<s2-</sup>, ions on anod ic and cathodic reactions on iron in 5 M KOH were studied. It was shown that a concentration ofthese ions of 10<sup>3-</sup>M inhibits the anodic iron dissolution reaction 2-3 times, while no effect on the hydrogen evolution reaction was observed. The effect was explained by the underpotential desposition of adatoms of the metal complexing ions on the iron electrode. -- AATA
pub_id
26872