26860
Accession Number
21507
Compiler
Black, James
Title Of Article Chaper
Known and new corrosion products on bronzes: their identification and assessment, particularly in relation to organic protective coatings
Title Of Journal Book
Recent advances in the conservation and analysis of artifacts. Jubilee conservation conference, London 6-10 July 1987
Pages
97-104
Publisher
University of London. Institute of Archaeology. Summer Schools Press
Publisher City
London
ISBN
0-9512429-0-3
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph
Literature Level
Analytic
Meeting
Jubilee conservation conference
Meeting City
London
Abstract
Extensive analyses of outdoor bronzes in Augsburg and Nuremberg (both in Western Germany) have shown that the methodical starting point for determining corrosion products on this type of bronze must be improved. X-ray diffractometric analyses provide an extensive spectrum of inorganic copper, lead, and calcium compounds, some of which are already known and others which have not been described until now. Additionally, investigations using gas chromatography/mass spectrometry allow the identification of various metal soaps and other purely organic products. With the help of these results it is possible to identify both older and younger protective coatings. A warning can be derived from the presence of copper soaps (i.e. copper salts of fatty acids) against the use of waxes and oils which are not acid-free.
Keywords
Bronze Outdoor Corrosion;Corrosion Product Identification; Corrosion X-ray diffraction (XRD);Corrosion Gas chromatography mass Spectrometry; Copper Soap;Bronze Protection Coating;Augsburg; Nuremberg AATA
pub_id
26860
Meeting Date
19870706-19870710