26685
Accession Number
25493
Author
Davenport, Derek A.; Howe-Grant, Mary; Srinivasan, Viswanathan
Author Affiliation
Purdue University;Purdue University;Purdue University
Title Of Article Chaper
Musical Molecular Weights and Other Non-Linear Properties of Gases
Title Of Journal Book
Journal of chemical education
Volume
56
Pages
523-525
Collation
3 p. : ill.
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
The fact that the classical gas laws are independent of the chemical nature of the gas is explicitly mentioned in all introductory texts and it is implicitly verified in many freshmen laboratory experiments. Graham's Laws of Effusion and Difussion introduce the experimental linear dependence of rate on the inverse square root of the molecular weight though theoretical derivations and putative experimental verifications are more complex than is commonly allowed. More advanced freshmen texts such as Mahan treat also of the viscosity, thermal conductivity, and diffusion of gases as do some supplementary paperbacks such as those by Cowling and by Hildebrand. Experimental study of these phenomena is, however, commonly left to the physical chemistry laboratory. This article describes simple ways in which the thermal conductivity, viscosity, and velocity of sound propagation of various gases can be semi-quantitatively measured (or demonstrated) at the freshman level. Recognition of the complex and decidedly non-linear ways in which these properties vary with the chemical nature of the gas is both salutary and, with a little effort, insightful. In particular, transport properties provide a useful entry to relative molecular parameters and the velocity of sound propagation in various gases provides a valuable macroscopic feeling for the magnitude of the microscopic root mean square velocity of molecules in those same gases.
Keywords
molecular weight;non linear;gas;viscosity;velocity;thermal conductivity; sound
pub_id
26685