24664
Accession Number
29676
Editor
Bridgland, Janet
Title Of Article Chaper
Corrosion and conservation of lead in sea water
Title Of Journal Book
ICOM committee for conservation, 11th triennial meeting in Edinburgh, Scotland, 1-6 September 1996: Preprints
Pages
884-890
Collation
2 b&w figs., 3 tables, refs.
Reference Bibliography
22 bibliog. refs.
Publisher
James & James (Science Publishers) Ltd.
Publisher City
London
ISBN
1-873956-50-8
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph : Proceedings
Literature Level
Analytic
Meeting
ICOM Committee for Conservation triennial meeting (11)
Meeting Country
United Kingdom
Abstract
Analysis of the corrosion products on lead artefacts recovered from historic shipwreck sites not only identifies the nature of the patina but it also provides an insight into the processes of decay across the site. From a comparison of the mineralogy of the lead corrosion products and their thermodynamic stability constants, it is possible to obtain a corrosion map of the areas from which the artefacts were recovered. The corrosion maps correlate with the levels of extractable chloride obtained from desalination data during treatment of artefacts. This data has general applicability regardless of the historical period pertaining to the wreck since lead is nearly always present on wreck sites. Corrosion simulation experiments in normal sea water provide an insight into the competing kinetic and thermodynamic forces that control the rate of deterioration of lead. The electrochemical data assists in the interpretation of the differences in patina.
Keywords
Archaeology; Excavation object; Underwater archaeology; Deterioration; Corrosion; Sea; Lead; Analysis
pub_id
24664
Meeting Date
19960901-19960906