23336
Accession Number
21093
Author
Davidson, R.S.; Meek, R.R.
Title Of Article Chaper
Photodegradation of polyethylene and polypropylene in the presence and absence of added titanium dioxide
Title Of Journal Book
European polymer journal
Volume
17
Pages
163-167
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
The durabilities of polyethylene and polypropylene, in the presence and absence of added titanium dioxide, towards photodegradation have been assessed by the rate of oxygen absorption upon irradiation, measurement of photo-induced carbonyl compound and hydroperoxide formation using IR spectroscopy, and by measuring the change in tensile propertics caused by irradiation. Measurement of carbonyl compound and hydroperoxide formation by IR spectroscopy is suitable for polyethylene but not for polypropylene. The most sensitive method of following degradation appears to be the measuring of change in tensile properties. In general, the lower the photo-reactivity of added titanium dioxide, the greater its protecting action provided that the pigment is used at sufficiently high loading. The manner in which a pigment is dispersed in a polymer affects the performance of the pigment as a stabilizer. -- AATA
pub_id
23336