23184
Author
Rivenc, Rachel; Schilling, Michael R.; Learner, Tom
Editor
Bridgland, Janet
Title Of Article Chaper
The potential for applying evaporation kinetics to the study of art and archaeological materials
Title Of Journal Book
ICOM Committee for Conservation, ICOM-CC, 15th Triennial Conference New Delhi, 22-26 September 2008: preprints
Pages
874-884
Publisher
Allied Publishers PVT
Publisher City
New Delhi
ISBN
9.79E+12
Language Of Text
English
Literature Type
Monograph : Proceedings
Literature Level
Monographic
Meeting
ICOM Committee for Conservation, ICOM-CC (2008 : 15th : New Delhi)
Meeting City
New Delhi
Meeting Country
India
Abstract
Kinetic evaluation of thermogravimetry data is a simple tool routinely used in the industry to predict materials’ performance and longevity. Its potential in the field of conservation science was tested through application to the understanding of the ageing behavior of beeswax used as a paint medium on ancient mummy shrouds and Fayum portraits. Individual components of beeswax were subjected to dynamic thermogravimetry, and two methods of kinetic analysis based on n<sub>th</sub>-order models were employed to assess their evaporation rates. The composition of thermally-aged beeswax, determined by GC/MS analysis, was compared with kinetic predictions as well as to a naturally-aged sample. The results showed that although it is impossible to accurately predict the volatility at room temperature for individual components of beeswax due to their high molecular weight, relative trends and ranking of the volatility of the compounds can be obtained which help explain and predict qualitative compositional changes over time.
Keywords
thermogravimetry; kinetic evaluations; volatility; beeswax; alkyds; acrylic emulsion additives
pub_id
23184
Meeting Date
20080922-20080926