21987
Accession Number
16525
Title Of Article Chaper
Effect of heat treatment on the crystallization of cuprous oxide in glass
Title Of Journal Book
Glass technology
Volume
22
Issue
1
Pages
24-33
Literature Type
Serial
Literature Level
Analytic
Abstract
The effects of heat treatment temperature and time on the rates of nucleation and growth, morphology, and color of cuprous oxide crystals developed in a copper lead alkali silicate glass were investigated. On cooling a melt to the appropriate temperature, the crystallization of cuprous oxide starts at about 870°C, i.e. about 360 centigrade degrees below its melting point. The temperatures of maximum crystal nucleation and growth are well separated making the control of the crystallization process easily accessible. The nucleation process is essentially completed in a very short time after heat treatment. The isothermal growth of the cuprous oxide crystals proceeds by diffusion-controlled and coarsening mechanisms in the early stage of crystallization and by the coarsening mechanism alone in the later stage. Cuprous oxide crystallizes out in the form of yellow cubes below 550°C and transforms to the stable red dendritic form at heat treatment temperatures higher than 650°C. Both these forms are known from the first millennium B.C. -- AATA
pub_id
21987