21849
Accession Number
27175
Author
Waller, R. Robert;Stairs, Robert A.;Miller, Tom
Author Affiliation
Canadian Museum of Nature. Conservation Section;Trent University. Department of Chemistry;Canadian Museum of Nature. Conservation Section
Title Of Article Chaper
Improving the selectivity of a selective dissolution process: a solution for removing calcite from fluorapatite
Title Of Journal Book
Collection forum
Volume
8
Issue
1
Pages
22-34
Collation
3 figs., 2 tables, 1 appendix
Reference Bibliography
9 refs.
Publisher
Society for the Preservation of Natural History Collections
Publisher City
Pittsburgh
ISSN
0831-4985
Language Of Text
English
Language Of Summary
English
Literature Type
Serial
Literature Level
Analytic
Abstract
A solution has been formulated which is capable of dissolving calcite from fluorapatite without causing damage to fluorapatite surfaces. This solution has a pH of 3.7 which is the point of maximum difference in the molar solubilities of calcite and fluorapatite. It was formulated to be just saturated with fluorapatite. Tho solution contains 0.100 <i>mo</i>/L<sup>-</sup>1 of the disodium salt of ethylenediamine tetraacetic acid, 0.050 <i>mo</i>/L<sup>-</sup>1 of calcium chloride, 1.5 × 10<sup>-</sup>5 <i>mo</i>/L<sup>-</sup>1 of sodium dihydrogen phosphate, 5 × 10<sup>-</sup>6 <i>mo</i>/L<sup>-</sup>1 of sodium fluoride, and a buffer mixture, 0.100 <i>mo</i>/L<sup>-</sup>1 of sodium formate with enough free formic acid to achieve the pH required. Experimental determinations of dissolution rate and scanning electron micrographs of treated surfaces confirm that the solution is capable of dissolving calcite at a reasonable rate without damaging fluorapatite crystal surfaces.
Keywords
calcite;dissolution;fluorapatite -- CAL
pub_id
21849