20089
Accession Number
27860
Editor
Vandiver, Pamela B.; Druzik, James R.; Wheeler, George Segan; Freestone, Ian C.
Title Of Article Chaper
Pore potential and durability of limestone at the Sphinx
Title Of Journal Book
Materials issues in art and archaeology III: symposium held 27 April-1 May 1992, San Francisco
Volume
267
Pages
917-923
Collation
4 figs., 1 table
Reference Bibliography
12 refs.
Publisher
Materials Research Society
Publisher City
Pittsburgh
ISBN
1-55899-162-X
ISSN
0272-9172
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph
Literature Level
Analytic
Meeting
Materials Research Society Symposium
Meeting City
San Francisco
Abstract
In mercury porosimetry of limestone two hystereses are generated. A PV-diagram for initial intrusion and extrusion reveals one hysteresis as entrapment of mercury in large cavities that are connected to the exterior through narrow channels. The other hysteresis is a loop (HL) enclosed between the extrusion and reintrusion curves which indicate narrow channels. An HL is unique to a stone. The thermodynamic work (W) calculated as SIGMAPDELTAV, is W<sub>I</sub>, W<sub>E</sub>, W<sub>RE</sub>, W<sub>HY</sub>, and W<sub>T</sub> for the initial intrusion, extrusion, reintrusion, the hysteresis loop, and the entrapment, respectively. The pore-potential (U) defined as U=W<sub>I</sub>- W<sub>E</sub>=W<sub>T</sub>+W<sub>HY</sub> regulates the volume and rate of movement of water through the pores which in turn determines the stone's durability. Microporous stones are highly susceptible to weathering and have a large value for W<sub>HY</sub>. W<sub>HY</sub> in association with the W<sub>T</sub> can be related to the durability factor (DF) as DF=W<sub>T</sub>/(W<sub>T</sub>+W<sub>HY</sub>). The DF values, thus obtained, accurately reflect the observed condition of the strata of the Sphinx. -- CAL
Keywords
pore;limestone;Sphinx -- CAL
pub_id
20089
Meeting Date
19920427-19920501