19429
Accession Number
27828
Author
Mayhew, Frances Whitaker;Block, Ira
Editor
Vandiver, Pamela B.; Druzik, James R.; Wheeler, George Segan; Freestone, Ian C.
Author Affiliation
University of Delaware;University of Maryland
Title Of Article Chaper
Changes in the infrared absorbance and color of aged cellulose film
Title Of Journal Book
Materials issues in art and archaeology III: symposium held 27 April-1 May 1992, San Francisco
Volume
267
Pages
459-469
Collation
7 figs., 3 tables
Reference Bibliography
22 refs.
Publisher
Materials Research Society
Publisher City
Pittsburgh
ISBN
1-55899-162-X
ISSN
0272-9172
Language Of Text
English
Language Of Summary
English
Literature Type
Monograph
Literature Level
Analytic
Meeting
Materials Research Society Symposium
Meeting City
San Francisco
Abstract
The accelerated aging of unplasticized cellophane film specimens was conducted at temperatures ranging from 80 to 150°C in a dry, forced-air convection oven for various periods of time. Cellophane was selected because it is regenerated cellulose, is transparent, and is manufactured to very close tolerances. Colorimetric evaluation showed increasing discoloration which could be partially reversed by rinsing in deionized water. The infrared spectra of samples aged within this temperature range show the same changes, dependent upon aging time. This indicates that the species formed in the films at temperatures above and below the boiling point of water are the same, and that the moisture content of the films may affect the reaction rate, but not the mechanisms. The observed data in the visible region fit the standard pseudo-first-order kinetics model and are in excellent agreement with those determined for both the color change of cotton and the ultraviolet absorbance of cellophane under similar conditions.
Keywords
aged;cellulose;film;infrared;absorbance -- CAL
pub_id
19429
Meeting Date
19920427-19920501