19985
Accession Number
19891
Author
Wilson-Yang, K.M.; Burns, G.
Author Affiliation
Lash Miller Chemical Laboratories. University of Toronto. 80 St. GeorgeSt. Toronto. Ont. Canada M5S 1A1
Title Of Article Chaper
The x-ray photoelectron spectroscopy of ancient murals in the tombs at Beni Hasan, Egypt
Title Of Journal Book
Canadian journal of chemistry
Volume
65
Issue
5
Pages
1058-1064
Collation
3 figs., 3 tables, 23 refs.
Publisher
National Research Council of Canada
Publisher City
Ottawa
ISSN
0008-4042
Language Of Text
English
Language Of Summary
English;French
Literature Type
Serial
Literature Level
Analytic
Abstract
The once colourful mural paintings at the Beni Hasan tombs (ca. 2100 B.C.), an important Egyptian archaeological site, are covered with an obscuring grey deposit. To study this surface degradation, x-ray photoelectron spectra of fragments from the painted walls have been collected. Three types of surfaces were identified. A preliminary mechanism for opaque layer formation is proposed. It suggests that the principal physicochemical processes are adsorption of water in the presence of carbon dioxide, followed by dissolution of the substrate walls upon which the murals were painted. This mechanism is consistent with the finding that mural deterioration is recent; it also indicates that deterioration is progressive, continuous, and cumulative. Relatively recent efforts in removing obtrusive surface layers with dilute hydrochloric acid (HCl) were found to be performed carefully; there was no evidence of excess chlorides on cleaned surfaces. However, this finding does not provide a guarantee that murals were undamaged by hydrochloric acid (HCl) below the surface. It does suggest that progressive damage due to the formation of hygroscopic calcium chloride (CaCl<sub>2</sub>) on the surface has been avoided. -- AATA
Keywords
X-ray photoelectron(XPS);Painting;Mural;Deterioration; Beni Hasan, Egypt; Tomb AATA
pub_id
19985