17977
Accession Number
27359
Author
Skoulikidis Th; Charalambous, D.
Title Of Article Chaper
Preuves pour le modele de la pile galvanique du mecanisme de la sulfatation des marbres
Title Of Journal Book
Ve congres international sur l'alteration et la conservation de la pierre. Actes. Vth international congress on deterioration and conservation of stone. Proceedings, lausanne, 25-27-9, 1985
Pages
547-551
Publisher
Presses polytechniques romandes
Publisher City
Lausanne
ISBN
2-88074-085-1
Language Of Text
French
Language Of Summary
French
Literature Type
Monograph
Literature Level
Analytic
Meeting
Deterioration and conservation of stone. 5.
Meeting City
Lausanne
Abstract
In previous studies the authors presented the hypothesis and proved both directly and indirectly that marble sulfation takes place in the same way as metal corrosion. The model consists of a galvanic battery with, as negative pole, marble, positive pole: SO<sub>2</sub>/O<sub>2</sub>, and moisture, and with a solid electrolyte, gypsum. The determining stage for speed of sulfation after a thickness of gypsum of 300 A is the diffusion in solid state of the Ca<sub>2</sub><sup>+</sup>. The present work presents additional proof of this model. To protect marble against sulfation, we used some of the same anticorrosive paints that protect metal against corrosion. To be more precise, we used coal tar epoxy and chlorinated rubber (paint brands), and we found a decrease in accelerated attack by SO<sub>2</sub>. The attack continued when the weight of the test tubes was increased, and EPMA identified the presence of gypsum on and/or in the protective film. It is interesting to note that the protection is many times more satisfactory with coal tar epoxy than with the pigmentless epoxy, and that, during the experiments, the film did not break into fissures in the same length of time as pigmentless epoxy does, or other such polymer protective films. Naturally, the color of these paints precludes their use on the surface of monuments.
Keywords
Stone, marble; stone, protection coating; stone, deterioration chemical corrosion; stone, deterioration; ICCROM
pub_id
17977
Meeting Date
19850925-19850927
Title Translation
Tests for the galvanic pile model of the sulphatation mechanism of marbles