16438
Accession Number
23391
Title Of Article Chaper
Weathering of bronze in sandy soil. A corrosion study
Title Of Journal Book
Angewandte Chemie
Volume
68
Pages
201-11
Literature Type
Serial
Literature Level
Analytic
Abstract
Exptl. results are reported for completely corroded bronzes, samples in an advanced state of corrosion, patina formation, leaching of Cu from patina, identification of dissolved metals, and decompn. of bronzes in the absence of chlorides. The end product of corrosion is a more or less pure stannic acid. Cu, Pb, Zn, and Ni are leached almost completely and fixed in the soil. Fe, Al, phosphate,and humus can migrate from the soil liquid to the residual stannic acid. CO<sub>2</sub> and O<sub>2</sub> content of ground water controls, in the main, the rate of corrosion. The bronze samples include historical finds. -- AATA
pub_id
16438