15877
Accession Number
30250
Author
Stolow, Nathan
Title Of Article Chaper
Action of solvents on dried linseed oil films
Title Of Journal Book
Nature
Volume
179
Issue
16
Pages
579-580
Reference Bibliography
Bibliog.: p. 580
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
This short article describes solvent swelling, deswelling and leaching of linseed oil films. Changes in thickness of fixed films are measured with an apparatus similar to a parallel plate viscometer. Free film thicknesses were observed under a measuring microscope. Linseed oil films are random, amorphous structures, low molecular units diffuse into the solvent phase. Degree of swelling at equilibrium depends on the solvent. Results are analysed according to cohesive energy densities and solubility parameters. Degree of swelling plotted against solubility parameter gives a resonance curve. 9.3 units is the solubility parameter for films of dried linseed oil. Solvents close to this parameter have the greatest swelling action. Rates of swelling or diffusion can be estimated using Fick's Law of diffusion for a semi-infinite solid. A similar equation gives deswelling data for linseed oil films. Rate of diffusion of solvent increases with temperature and indicates a simple physical absorption of the solvent. Pigments slow the rate of diffusion. Solvents with low swelling and leaching capacity are best for the cleaning of paintings.
Keywords
Painting, cleaning; solvent, absorption; solvent, solubility; oil, linseed -- ICCROM
pub_id
15877