15178
Accession Number
7030
Title Of Article Chaper
Changes in solubility and removability of varnish resins with age
Title Of Journal Book
Bulletin of the AIC
Volume
15
Issue
2
Pages
17-26
Literature Type
Serial
Literature Level
Analytic
Abstract
A series of mixtures based on cyclohexane, toluene and acetone have been employed to investigate the solvent power needed to remove various varnish resins in the course of photo-chemical deterioration. Under ordinary conditions of exposure, dammar and mastic resins tend to reach a maximum degree of oxidation at which time mixtures of no greater solvent power than 60/40 v/v toluene/acetone are needed to remove the aged coatings. Polycyclohexanone polymers tend to lose their solubility more slowly than the two natural resins but may in time require solvents of higher solvent power to remove them. In contrast, the two highly stable polymers, polyvinylacetate and Acryloid B-72 essentially maintain their solubility and removability in the solvents in which they were originally soluble, mixtures of lower solvent power than toluene. An investigation of the actual percentage of the resins dissolved by the various solvent mixtures indicates that, in the case of polyvinylacetate and Acryloid B-72, solubility and removability are closely related. In contrast, solubility of the natural and polycyclohexanone resins changes more gradually with changes in solvent power, implying that their ease of removal depends more on rate of attack than upon the amount of resin dissolved. -- AATA
pub_id
15178