13384
Accession Number
12895
Title Of Article Chaper
Mineralogical Stabilization of High-Magnesium Calcite: Ceochemical Evidence for Intracrystal Recrystallization Within Holocene Porcellaneous Foraminifera
Title Of Journal Book
Journal of Sedimentary Petrology
Volume
63
Issue
2
Pages
261-274
Collation
14 p. : ill.
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Mineralogical stabilization of porcellaneous foraminifera is known to consist of chemical change without textural alteration at any scale. However, the nature of the alteration process has not been fully reconciled. Porcellaneous foraminifera from the freshwater diagenetic zone of two small islands in the Schooner Cays, Bahamas, are in the midst of Mg loss and delta<sup>18</sup>O change with no textural alteration at any scale. These data indicate that the mineralogical stabilization process, or recrystallization, is a repetitive intracrystal incongruent dissolution-precipitation reaction. Each recrystallization produces a calcite with a slightly lower Mg content than its predecessor. The rate of stabilization is dependent on time and hydrologic flux; older phreatic-zone material is the most altered and younger vadose-zone material is the least altered. Numerical modeling of the chemical diagenesis indicates that the molar water : rock ratio of a single recrystallization is less than 1, and the resultant precipitate is not in equilibrium with the ambient pore waters. Repetitive recrystallizations, however, eventually yield a mineralogically stable low-Mg calcite (LMC) that is in equilibrium with the bulk pore waters. Complete mineralogical stabilization to LMC should occur at cumulative molar water : rock ratios of about 16 and will require ten to hundreds of recrystallizations, each reducing Mg content by no more than 0.1 mole per thousand. The large number of recrystallizations with incrementally small chemical changes per recrystallization make alteration of these foraminifera significantly different from single-step recrystallization of other types of bioclasts. Thesimultaneous modeling of Mg concentrations and oxygen isotopic compositions requires a Mg partition coefficient (D<sub>Mg</sub>) between 0.0001 and 0.0003. These values are two orders of magnitude less than that generally assigned to calcite precipitation from a large fluid reservoir, and they suggest that D<sub>Mg</sub> is dependent on the type and scale of reaction, though the nature of that dependency is unknown.
Keywords
mineral;stabilization;magnesium;calcite;crystallization
pub_id
13384