13283
Accession Number
3130
Author
Parks, Edwin J.; Herbert, R.L.
Title Of Journal Book
A Source of Error in Paper Extract pH Determinations: Contact between Paper and Reference Electrodes
Collation
14 p. : tables
Reference Bibliography
Includes bibliog. refs.
Report Number
NBSIR 75-915
Publisher
U.S. Department of Commerce. National Bureau of Standards
Publisher City
Washington
Language Of Text
English
Literature Type
Monograph
Literature Level
Monographic
Abstract
If the reference electrode of a pH meter is permitted to contact the paper suspended in an aqueous medium, the pH observed is lower than that observed with no contact. The effect has been observed with papers of widely different pH, and varies in magnitude with the proximity of contact and with different papers. The problem can be avoided by taking measurements on decanted equilibrium solutions instead of suspensions of paper. The cause of this effect may be analogous to the suspension effect in colloidal systems. -- CAL
Keywords
Acidity;Decantate;Electrode;Error;Extract;Paper;pH;suspension CAL
pub_id
13283