12786
Accession Number
31197
Title Of Article Chaper
The first wine and beer: chemical detection of ancient fermented beverages
Title Of Journal Book
Analytical chemistry
Volume
65
Issue
8
Pages
408A-413A
Collation
6 figs.
ISSN
0003-2700
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Transmission and diffuse-reflectance Fourier transform infrared spectrometry (DRIFTS) were used to examine acetone extracts of red deposits in a jar recovered from Godin Tepe, located in the Zagros Mountains of western Iran and dating approximately 3500-2900 BC (Period V, the late Uruk period). These spectra were compared with those obtained from the residue found in a Nubian wine amphora from Gebel Adda, and from naturally occurring tartaric acid. The close similarities among the three sets of spectra, as well as a positive reaction by all three sources to the Feigl spot test which is highly specific for tartaric acid, establish that the residue in the Godin Tepe jar contains tartaric acid which occurs in grapes and grape products. This finding and accompanying archaeological data indicate that the Godin Tepe jar very probably contained wine. Pale yellow deposits in incisions in the interior of a late Uruk double-handled jug from one of the same rooms containing the wine jars at Godin Tepe was shown to be an oxalate, most likely calcium oxalate. This compound is a principal component of beerstone and responded in a Feigl spot test for oxalate in the same manner as did scrapings from an Egyptian New Kingdom beer bottle and as did modern beerstone from a brewer's vat. Identification of oxalate in the Godin Tepe jug confirmed archaeological and pictographic evidence that the vessel was a beer container. Speculation is offered on the sources of the wine and beer once contained in these vessels.
pub_id
12786