12489
Accession Number
20135
Title Of Article Chaper
IRS-Untersuchung der degradierenden Wirkung von Licht und SO<sub>2</sub> auf pigmentiertes Papier
Title Of Journal Book
Mikrochimica Acta
Volume
1
Issue
3
Pages
87-94
Language Of Text
German
Language Of Summary
German;English
Literature Type
Serial
Literature Level
Analytic
Abstract
Paper samples provided with color layers containing various copper acetates were exposed to visible light with wavelengths above 340 nm (123,6 footcandles). Seventy-five hours of irradiation were sufficient to give rise to distinct physicochemical changes of the components as observed by infrared spectrometry. Treatment of the samples with gaseous sulfur-dioxide caused the degradation of the copper pigments as well as the simultaneous autoxidation of cellulose catalyzed by the copper ions present. On the basis of infrared spectra there is strong evidence for the formation of reddish-brown globules of Chevreul's salt, Cu<sub>2</sub>SO<sub>3</sub>.CuSO<sub>3</sub>.2H<sub>2</sub>O, as a consequence of sulfur-dioxide treatment. These findings are confirmed by x-ray diffraction techniques, indicating the presence of metallic copper produced by the reductive action of sulfur-dioxide. Similar globules were already found on decayed paper samples of original objects of illuminated graphic art. See also 19-1244. -- AATA
pub_id
12489
Title Translation
IRS-Investigations concerning the destructive effects of light and sulfur dioxide on mixtures of paper and copper pigments