11784
Accession Number
8447
Author
Davis, Neil P.; Garnett, John L.; Long, Mervin A.; Major, Geoffrey; Nicol, Kenneth J.
Editor
WILLIAMS, John C.
Other Author
Williams, John C.; Comstock, Joan M.
Title Of Article Chaper
Methods for enhancing ultraviolet and radiation grafting of monomers to cellulose and derivatives to improve properties of value to conservation
Title Of Journal Book
Preservation of Paper and Textiles of Historic and Artistic Value II
Pages
223-240
Collation
graphs, tables
Publisher
American Chemical Society
Publisher City
Washington DC
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Meeting
Symposium on preservation of paper and textiles of historic and artistic value. II
Meeting City
Washington DC
Abstract
UV was used to initiate grafting of styrene, methyl methacrylate, and ethyl acrylate to cellulose in the conservation of aged paper. To overcome homopolymerization, a styrene comonomer procedure was developed. The inclusion of organic acids in the grafting solution enhance grafting, thus reducing the total irradiation time that the cellulose is in contact with the solvent monomer solution. Analogous grafting to cellulose derivatives (i.e., the acetate) occurred in the presence of ionizing radiation and was accelerated by the presence of mineral acid. A mechanism for acid effects in both UV and gamma-ray grafting procedures was proposed. See AATA 18-1013.
Keywords
Ultraviolet, radiation; Gamma ray, radiation; Paper, examination ultraviolet; Paper, test
pub_id
11784
Meeting Date
19790910-19790912