11742
Accession Number
20146
Title Of Article Chaper
Inversion of marble sulfation - reconversion of gypsum films into calcite on the surfaces of monuments and statues
Title Of Journal Book
Studies in conservation
Volume
29
Issue
4
Pages
197-204
Collation
14 figs
Reference Bibliography
Includes bibliographic references
Publisher
International Institute for Conservation of Historic and Artistic Works
Publisher City
London
Language Of Text
English
Language Of Summary
French;German
Literature Type
Serial
Literature Level
Analytic
Abstract
The work combines the authors'observation that the details of marble statues that have already been lost from the calcite surface are preserved in the gypsum layer, with their research on the mechanism of marble sulfation, to lead to a consolidation of the gypsum, transforming it back to calcium carbonate (calcite) using carbonate ions in solution. Research shows the mechanism of the conversion of gypsum to calcite, the rate determining steps being the desorp tion and diffusion of COÈ7. The reproduction of the surface detail and the improvement of the mechanical properties were very satisfactory. See also AATA 19-1782, 19-1783, 20-1528, 20-1529, and 21-2123 for more information on marble sulfation.
Keywords
Cross-section, stone; stone, deterioration crust exfoliation; stone, deterioration chemical corrosion; stone, deterioration; stone, consolidation test; stone, consolidation; stone, conservation; stone, cleaning; stone, analysis; stone, impregnation technology; gypsum, technology; gypsum, conservation; gypsum, cleaning; stone, restoration; stone, patina; stone, marble. ICCROM -- ICCROM
pub_id
11742