10038
Accession Number
32855
Author
Evans, H.E.
Title Of Article Chaper
The role of oxide grain boundaries in the development of growth stresses during oxidation
Title Of Journal Book
Corrosion Science
Volume
23
Issue
5
Pages
495-506
Collation
12 p. : ills.
Reference Bibliography
Includes bibliographic references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
A model is described which identifies the oxide growth stresses observed in many systems with the diffusion of anions along oxide grain boundaries and the subsequent formation of an oxide intrusions at the oxide/metal interface. Detailed calculations are made of the elastic stress system within the metal and of the average stress developed in the oxide. For a Pilling-Bedworth ratio greater than unity, the oxide intrusion acts as a linear center of dilatation generating short-range tensile stresses within the metal and equivalent compressive stresses within the oxide. It is shown that the average value of the oxide stress increases with both the oxide grain size and with the lateral dimensions of the oxide intrusion.
Keywords
oxide;grain;boundary;development;growth;stress;oxidation
pub_id
10038