8736
Accession Number
32020
Title Of Article Chaper
Microbeam Characterization of Corning Archeological Reference Glasses: New Additions to the Smithsonian Microbeam Standard Collection
Title Of Journal Book
Journal of Research of the National Institute of Standards and Technology
Volume
107
Issue
6
Pages
719-727
Collation
9 p. : ills.
Reference Bibliography
Includes bibliographic references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
An initial study of the minor element, trace element, and impurities in Corning archeological references glasses have been performed using three microbeam techniques: electron probe microanalysis (EPMA), laser ablation ICP-mass spectrometry (LA ICM-MS), and secondary ion mass spectrometry (SIMS). The EPMA results suggest a significant level of heterogeneity for a number of metals. Conversely, higher precision and larger sampling volume analysis by LA ICP-MS indicates a high degree of chemical uniformity within all glasses, typically <2% relative (1[delta]). SIMS data reveal that small but measurable quantities of volatile impurities are present in the glasses, including H at roughly the 0.0001 mass fraction level. These glasses show promise for use as secondary standards for minor and trace element analyses of insulating materials such as synthetic ceramics, minerals, and silicate glasses.
Keywords
chemical;heterogeneity;electron;probe;microanalysis;analysis;glass;laser;ablation;icp-ms;microbeam;icp;microscale;characterization;seconday;ion;mass;spectrometry;archaeology
pub_id
8736