7880
Accession Number
22605
Title Of Article Chaper
Determining the Relative Age of Ballpoint Ink Using a Single-Solvent Extraction, Mass-Independent Approach
Title Of Journal Book
Journal of forensic science
Volume
34
Issue
5
Pages
1166-1182
Collation
17 p. : ill., 14 figs., 5 tables
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
Brunelle et al. (Journal of Forensic Sciences, Nov. 1987) recently reported a single-solvent extraction technique for determining the relative age of ballpoint ink entries on questioned documents. This technique was mass dependent, which means equal amounts of ink had to be removed from the document for all samples compared. This paper describes a modification of the previous procedure that makes the age determination independent of the amount of ink sampled for testing. The modified procedure involves extracting the inks with solvents, spotting the ink extract onto a thin-layer chromatographic plate, and then separating the dye components in a solvent system of ethyl acetate : alcohol : water (70 : 35 : 30 parts, respectively). The relative concentrations of the dye components are measured using a densitometer. The calculated ratios of the relative concentrations are independent of the amount of ink taken for analysis. Aging curves were prepared for four different ballpoint inks and two non-ballpoint inks. The effect of different papers on ink aging was determined, and the mass independence theory was verified. The feasibility for determining the relative age of non-ballpoint inks was also established.
Keywords
relative age;ballpoint ink;solvent extraction;mass independent; questioned documents;inks;extraction;ratios;paper; densitometry; non-ballpoint ink;thin layer chromatography
pub_id
7880