7530
Accession Number
33366
Title Of Article Chaper
The tin-mercury mirror: its manufacturing technique and deterioration processes
Title Of Journal Book
Studies in conservation
Volume
38
Issue
1
Pages
44271
Collation
15 figs., 2 tables
Reference Bibliography
17 refs.
ISSN
0039-3630
Language Of Text
English
Language Of Summary
English;French;German
Literature Type
Serial
Literature Level
Analytic
Abstract
Mirrors made of glass backed with a reflective coating of tin amalgam first came into general use in the 16th century. Production ceased around 1900. The mirrors were made by sliding glass over tinfoil flooded with mercury. The mercury reacts with tin to form a layer of crystals containing about 19 wt% of mercury alloyed with the tin. The voids between the crystals are filled with a fluid phase containing about 0.5% tin in mercury. This two-phase reflective coating changes with time; the crystals grow larger and cover a greater proportion of the glass surface, while mercury slowly evaporates. In time, tiny voids appear between glass and amalgam. The fluid phase also migrates to the bottom of the mirror. Corrosion of the amalgam produces tin dioxide and tin monoxide and releases liquid mercury from the solid phase. Amalgam mirrors contribute a few micrograms of mercury per cubic meter of air in a room. Measured values have all been far below the official toxic limit of 50 mug <sup>-3</sup>. The frames often contain drops of mercury and special precautions are necessary for safe transport, repair, and disposal of the mirrors. -- AATA
Keywords
Mirror; Glass; Deterioration; Corrosion -- ICCROM
pub_id
7530