6575
Accession Number
3172
Title Of Article Chaper
On the possibility of devitrification of ancient glass
Title Of Journal Book
J. Non-Cryst. Solids
Volume
29
Issue
2
Pages
207-214
Language Of Text
English
Literature Type
Serial
Literature Level
Analytic
Abstract
The question of whether some crystallization will take place in old glass during long-time storage (up to 1000 years) at low temperatures well below T<sub>g</sub> is considered theoretical. Evalua-tions for the systems, Na<sub>2</sub>O.SiO<sub>2</sub> and Li<sub>2</sub>O.2SiO<sub>2</sub>, are carried out using the model of homo-geneous and heterogeneous nucleation theory. For these systems a barely observable crystal-lized volume fraction will be reached at 300 K only after storage for astronomical periods (10<sub>6</sub>-10<sub>13</sub> years), depending on the number of heterogeneities and the contact angle of heterogeneity.If the observed strong influence of H<sub>2</sub>O content in glass on crystallization is also taken into ac-count, crystallization will not take place for at least 1000 years of storage at 300 K. This limiting value is close to archaeological periods and will therefore merit careful attention in further investigations. -- AATA
pub_id
6575