A study of the alterations caused by chemical weathering on carbonatic outcrops in the south of France (near Marseilles) has revealed the presence of gypsum crusts. An analogy with carbonatic surfaces (marbles and limestones) located in urban areas (monuments and buildings) has therefore been evidenced. An analytical investigation of the morphology, typology, and inner structure of the crusts found is presented in this paper. Furthermore, reference is also made to the identification of fly ash particles embedded in the altered layer: this occurrence enables a limitation of the crust-growth period to the present century. Some hypotheses as to the role played by these particles in the formation of the altered layer have also been advanced. In this regard, the study of particles emitted by coal combustion, one of the major sources of energy, as far as their environmental impact is concerned, is of unquestionable importance.