4902
Accession Number
1064
Title Of Journal Book
Electronic Effects in Elimination Reactions. VIII. The E2 Reaction of 2-Arylethyl Fluorides
Collation
23 p. : ill.
Reference Bibliography
Includes bibliographical references
Language Of Text
English
Literature Type
Unpublished
Literature Level
Monographic
Abstract
The rates of bimolecular elimination from a series of 1-fluoro-2-arylethanes, 1,1-difluoro-2-arylethanes, and 1,1, 1-trifluoro-2-arylethanes have been measured in t-butyl alcohol using potassium t-butoxide as the base. The absolute rate of the reaction and the Hammett rho value for the elimination both increase with the number of fluorines. Values for the latter are +3.24 for the fluoride, +3.56 for the difluoride and +4.04 for the trifluoride, indicating that the transition state is highly carbanionic in character, as is also indicated by a relatively low value of K<sub>H</sub>/K<sub>D</sub>.
Keywords
electronic;elimination;reactions;fluorides;2-Arylethyl fluorides; bimolecular
pub_id
4902