4834
Author
Freestone, I.C.; Meeks, N.D.; Middleton, A.P.
Title Of Article Chaper
Retention of phosphate in buried ceramics: an electron microbeam approach
Title Of Journal Book
Archaeometry
Volume
27
Issue
2
Pages
161-177
Literature Type
Serial
Literature Level
Analytic
Abstract
Elevated concentrations of P<sup<sup>b>2O<s</sup><sup<sup>b>5</sup><sup > <sup>of 2-12 wt<</sup>sup>% <sup>absol</sup><sup<sup>te </sup> <sup>were </sup> <sup>observed in t</sup> are enriched towards the surfaces in some cases and elemental correlations suggest precipitation of a crystalline calcium phosphate with a stoichiometry close to CaO . P<sub>2</sub>O<sub>5</sub>. Scanning electron microscopy with X-ray mapping showed P<sub>2</sub>O<sub>5</sub> to be dispersed in the ceramic matrix on a very fine scale, while X-ray diffraction detected no crystalline phosphate. Parallels are drawn with the precipitation of phosphate in the surfaces of weathered glass. It is concluded that the amorphous phases produced on firing behave as chemically-active substrates which facilitate the adsorption or precipitation of very fine-grained calcium phosphate from the burial environment. See also AATA 20-1992. -- AATA
Keywords
ceramic analysis, ceramic provenance;Glass weathering, SEM, electron microprobe;Phosphate, glass corrosion, ceramic weathering AATA
pub_id
4834